Chemistry Letters p. 2173 - 2176 (1992)
Update date:2022-08-11
Topics:
Matsubara, Seijiro
Takahashi, Hideya
Utimoto, Kiitiro
Both enantiomers of 1,2-alkanediols were prepared by the diastereocontrolled reduction of ketones containing (R)-6-methyl-1,3-oxathiane moiety as a chiral auxiliary; reduction with Zn(BH4)2 selected one diastereoface to give one diastereomer and that with YCl3-NaBH4 produced another diastereomer selectively.
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