Tetrahedron Letters p. 2243 - 2246 (1993)
Update date:2022-08-10
Topics:
Taber, Douglass F.
Louey, James P.
Lim, Julie A.
Diene 8, under cyclozirconation conditions, rapidly dimerizes to 10.This dimerization is reversible, slowly at room temperture and rapidly at 75 deg C.After equilibration, the dominant product is 12, the product of intramolecular cyclozirconation. Key words: carbocyclization, cyclometallation, cyclozirconation, diastereoselective, reversible, equilibrating
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