Tetrahedron Letters p. 8419 - 8422 (1993)
Update date:2022-08-11
Topics:
Tuchscherer, G.
A chemoselective ligation via oxime bond formation is used for the chemical synthesis of template assembled peptides according to the TASP (Template Assembled Synthetic Proteins) approach.Aminooxyacetylation of the multifunctional partial sequence Lys- Arg- Asp- Ser of lactoferrin and subsequent condensation in aqueous solution with a topological template containing four selectively addressable aldehyde functions as attachments sites gives readily access to the TASP molecule. - Keywords: Template Assembled Synthetic Proteins; chemoselecive ligation; multifunctional peptide; topological template; oxime bond formation
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