Journal of Organometallic Chemistry p. 143 - 148 (1995)
Update date:2022-08-11
Topics:
Herzog, U.
Roewer, G.
Paetzold, U.
Partial hydrogenation of methylchlorodisilanes and hexachlorodisilane to methylchlorohydrogendisilanes and chlorohydrogendisilanes respectively, is possible by the use of tri-n-butylstannane.Electron-pair donators catalyse the hydrogenation reaction.The 29Si NMR chemical shifts and coupling constants 1JSiH of some new methylchlorohydrogendisilanes are reported.Keywords: Silicon; Catalysis; Partial hydrogenation
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