Helvetica Chimica Acta p. 1331 - 1332 (1986)
Update date:2022-08-11
Topics:
Chiang, Yvonne
Kresge, A. Jerry
Capponi, Marco
Wirz, Jakob
The photohydration of phenylacetylene yields acetophenone enol as a transient primary product which was detected by flash photolysis.The identification of the transient intermediate rests on a quantitative comparison of its decay kinetics with that of authentic acetophenone enol generated by Norrish type-II photoelimination from γ-hydroxybutyrophenone in aqueous HCl and aqueous AcOH buffer solutions.
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