Heterocycles p. 1753 - 1757 (1998)
Update date:2022-08-31
Topics:
Honda, Toshio
Mizutani, Hirotake
Treatment of 2,3-epoxy alcohols with tetramethylammonium triacetoxyborohydride afforded the ring-opening products at the C-3 position, regioselectively, where the presence of Me4NBH(OAc)3 increased the reaction rate and regioselectivity by forming the chelation intermediate between the metal center and the epoxy alcohol oxygens.
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