Journal of Organic Chemistry p. 571 - 577 (1981)
Update date:2022-08-12
Topics:
Olah, George A.
Yu, Simon
Liang, Gao
Matseescu, Gheorghe D.
Bruce, Mark R.
et al.
For exploration of the in vitro formation of the potential carcinogenic alkylating agents and particularly the reactive ionic intermediates derived from formaldehyde-hydrogen halides and haloalkyl ethers, their protolytic ionization under stable-ion conditions in low-nucleophilicity solutions was studied.The preparation, a NMR spectroscopic structural study, and the alkylating ability of a series of (haloalkyl)oxonium and (haloalkyl)carboxonium ions, including the previously elusive (fluoromethyl)- and (chloromethyl)oxonium ions, are reported, indicating their potential bioalkylating ability.
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