C-CN BOND CLEAVAGE UNDER MILD CONDITIONS PROMOTED BY ELECTRON-RICH COBALT COMPLEXES

DOI: 10.1246/cl.1982.1707

Source and publish data:

Chemistry Letters p. 1707 - 1710 (1982)

Update date:2022-08-12

Topics:

Authors:

Ozawa, Fumiyuki

Iri, Kiyoshi

Yamamoto, Akio

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Article abstract of DOI:10.1246/cl.1982.1707

Electron-rich cobaltate dinitrogen complex, Li(Et2O)3 1, reacts with alkyl and aryl nitrile compounds causing the cleavage of C-CN bond under mild conditions to release hydrocarbons.Catalytic activity of the cobalt complex to isomerize allyl cyanide to crotononitrile is also noted.

Full text of DOI:10.1246/cl.1982.1707

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