Hydrolysis of O-isopropenyl glucopyranosides involves C-protonation and alkenyl ether cleavage and exhibits a kinetic influence of anomeric configuration

DOI: 10.1021/jo00100a015

Source and publish data:

Journal of Organic Chemistry p. 6167 - 6169 (1994)

Update date:2022-08-16

Topics:

Authors:

Chenault

Chafin Chafin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00100a015

Hydrolysis of O-isopropenyl α-glucopyranoside occurs by O-protonation and alkenyl ether (not glycosidic) C-O bond cleavage and proceeds in 10 mM salicylate buffer, at pH 3.0 and 25°C, 4.5 times faster than the similar hydrolysis of its β anomer.

Full text of DOI:10.1021/jo00100a015

Products guided by the article

Product name:DEXTROSE

Cas No:492-61-5

R&D Labs maybe for 492-61-5

Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
Xiamen Hisunny Chemical Co.,Ltd

website:http://www.hisunnychem.com

Contact:+86-592-3327115

Address:Unit 603,No.879,Xiahe Road,Meixin Building,Xiamen,China
Changsha Easchem Co.,Limited

website:http://www.easchem.com

Contact:+86-731-89722861 89722891

Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.

Relevant to this article

Diastereoselective cycloadditions and transformations of N -alkyl and N -aryl maleimides with chiral 9-anthrylethanol derivatives

Doi:10.1021/jo101437b
(2010)
Design and synthesis of photoactive ionic amorphous molecular materials

Doi:10.1039/c1jm11735a
(2011)
1,2-Bis(dimethylsilyl)phenylidene bridged zirconocene and hafnocene dichloride complexes as precatalysts for ethylene polymerization

Doi:10.1016/j.jorganchem.2017.11.010
(2018)
Photoinduced molecular transformations. Part 156. New photoadditions of 2-hydroxy-1,4-naphthoquinones with naphthols and their derivatives

Doi:10.1016/0040-4020(94)01026-V
(1995)
High pressure phase transformations in neodymium studied in a diamond anvil cell using diamond-coated rhenium gaskets

Doi:10.1088/0953-8984/11/34/303
(1999)
8-Phenyl-Substituted Dipyrromethene·Bf₂ Complexes as Highly Efficient and Photostable Laser Dyes

Doi:10.1021/jp0312464
(2004)

Article Doi