Generation and Transformation of the Propellane Skeleton by Thermal Rearrangements

DOI: 10.1016/S0040-4039(00)74405-4

Source and publish data:

Tetrahedron Letters p. 8353 - 8356 (1994)

Update date:2022-08-23

Topics:

Authors:

Kraemer, Guido

Kolshorn, Heinz

Meier, Herbert

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Article abstract of DOI:10.1016/S0040-4039(00)74405-4

In a sequence of unexpected thermal rearrangements the strained monocyclic alkyne 4 is transformed into the tricyclic system 5 which yields in a flash vacuum pyrolysis again a monocyclic compound 10.

Full text of DOI:10.1016/S0040-4039(00)74405-4

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