Journal of the Chemical Society. Chemical communications p. 165 - 166 (1983)
Update date:2022-08-17
Topics:
Sato, Fumie
Tanaka, Youichi
Sato, Masao
A 1,3-silyl group shift from carbon to oxygen occurs readily when β-hydroxyvinylsilanes are treated with catalytic amounts of sodium hydride in hexamethylphosphoric triamide, thus providing the first demonstration of the rearrangement of silicon from sp2-carbon to oxygen.
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