Synthesis of 3-aminopyrocatechol via lithiated intermediates

Article abstract of DOI:10.1080/00397919708004075

We report the synthesis of 3-aminopyrocatechol (7) through electrophilic amination of lithiated pyrocatechol, protected in the form of a ketal. For this purpose the lithiation reaction of protected pyrocatechol (1) was studied. The synthesis of compounds

Full text of DOI:10.1080/00397919708004075

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Synthetic Communications: An
International Journal for Rapid
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Organic Chemistry
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Synthesis of 3-
Aminopyrocatechol via
Lithiated Intermediates
Marieta Shopova a , Elka Vassileva b , Claude Fugier c
& E. Henry-Basch a
a Institute of Molecular Biology, Bulgarian Academy
of Sciences , 1113, Sofia, Bulgaria
b Laboratoire de Chimie Organométallique ,
Université Paris-Sud , 91405, Orsay, France
c ORIL , 13, rue Auguste Desgenétais, B.P. 17, 76210,
Bolbec, France
Published online: 22 Aug 2006.
To cite this article: Marieta Shopova , Elka Vassileva , Claude Fugier & E. Henry-
Basch (1997) Synthesis of 3-Aminopyrocatechol via Lithiated Intermediates, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 27:10, 1661-1667, DOI: 10.1080/00397919708004075
To link to this article: http://dx.doi.org/10.1080/00397919708004075
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