A convenient synthesis of the side-chain of sterols

DOI: 10.1016/0040-4039(95)02075-6

Source and publish data:

Tetrahedron Letters p. 29 - 32 (1996)

Update date:2022-08-11

Topics:

Authors:

Schmittberger

Uguen Uguen

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Article abstract of DOI:10.1016/0040-4039(95)02075-6

Potassium t-butoxide-induced Ramberg-Backlund rearrangement of chlorosulfones formed from a cyclopregnane-20-thiomethanol derivative has been shown to give Δ²²-unsaturated steroids with high trans stereoselectivity.

Full text of DOI:10.1016/0040-4039(95)02075-6

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