Enantioselective catalysis 94. The 'diphenyl effect' in the enantioselective hydrosilylation of acetophenone with diphenylsilane using Rh'5,5-diphenyl-2-(2-pyridinyl)oxazoline catalysts

DOI: 10.1016/0957-4166(95)00052-Q

Source and publish data:

Tetrahedron Asymmetry p. 653 - 656 (1995)

Update date:2022-08-17

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Authors:

Brunner Brunner

Henrichs

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Article abstract of DOI:10.1016/0957-4166(95)00052-Q

The 5.5-diphenyl-2-(2-pyridinyl)oxazolines 2a-e give ee values 9.6-34.2% higher than their unsubstituted counterparts 1a-e in the Rh-catalyzed enantioselective hydrosilylation of acetophenone with diphenylsilane.

Full text of DOI:10.1016/0957-4166(95)00052-Q

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