Enantioselective catalysis 94. The 'diphenyl effect' in the enantioselective hydrosilylation of acetophenone with diphenylsilane using Rh'5,5-diphenyl-2-(2-pyridinyl)oxazoline catalysts

DOI: 10.1016/0957-4166(95)00052-Q

Source and publish data:

Tetrahedron Asymmetry p. 653 - 656 (1995)

Update date:2022-08-17

Topics:

Authors:

Brunner Brunner

Henrichs

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0957-4166(95)00052-Q

The 5.5-diphenyl-2-(2-pyridinyl)oxazolines 2a-e give ee values 9.6-34.2% higher than their unsubstituted counterparts 1a-e in the Rh-catalyzed enantioselective hydrosilylation of acetophenone with diphenylsilane.

Full text of DOI:10.1016/0957-4166(95)00052-Q

Products guided by the article

Product name:(1-phenylvinyloxy)(diphenyl)silane

Cas No:51276-66-5

R&D Labs maybe for 51276-66-5

Ningbo Distant Chemicals Co.,Ltd

Contact:86-574-27862490,27862438

Address:5F-3,#54 DaShaNi street,Ningbo,CHINA
Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road
Jinzhou Jiutai Pharmaceutical Co.,Ltd

Contact:+86-0416-5179890

Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601
KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road

Relevant to this article

Iron-Catalyzed Synthesis of Sulfur-Containing Heterocycles

Doi:10.1021/acs.joc.6b01827
(2017)
Synthesis and antimicrobial activity of 5,5′-dimethyl-2-oxido-[1,2,3] -dioxaphosphorinane-2-yl-amino carboxylates

Doi:10.1002/hc.20426
(2008)
Observation of pseudorotamers of two unconstrained Wittig intermediates, (3RS,4SR)- and (3RS,4RS)-4-cyclohexyl-2-ethyl-3,4-dimethyl-2,2-diphenyl- 1,2λ⁵-oxaphosphetane, by dynamic ³¹P NMR spectroscopy: Line-shape analyses, conformatio

Doi:10.1021/ja974332o
(1998)
REMOVAL OF N-BENZYL- AND N-BENZYLOXYMETHYL SUBSTITUENTS FROM SUBSTITUTED URACILS WITH BORON TRIBROMIDE

Doi:10.1016/S0040-4039(01)83926-5
(1980)
Aliphatic amines modified CoO nanoparticles for catalytic oxidation of aromatic hydrocarbon with molecular oxygen

Doi:10.1016/S1872-2067(19)63413-3
(2019)
Cobalt-Based Metal-Organic Cages for Visible-Light-Driven Water Oxidation

Doi:10.1021/acs.inorgchem.1c00907
(2021)

Article Doi