Addition of Dimethylsilanediyl (Dimethylsilylene) to cis,cis-Hexa-2,4-diene: Evidence for a Concerted Vinylsilacyclopropane Rearrangement

DOI: 10.1039/c39850001149

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1149 - 1151 (1985)

Update date:2022-08-16

Topics:

Authors:

Lei, Deqing

Gaspar, Peter P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001149

The formation of cis-3,3-dimethyl-3-silahepta-1,4-diene as the major product from addition of dimethylsilanediyl (dimethylsilylene) to cis,cis-hexa-2,4-diene is believed to result from a concerted 1,5-sigmatropic hydrogen shift in the rearrangement of the vinylsilacyclopropane intermediate formed by concerted 1,2-cis-addition of the silanediyl.

Full text of DOI:10.1039/c39850001149

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2,4-HEXADIENE

Cas No:5194-50-3

R&D Labs maybe for 5194-50-3

Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
JiangXi Hong Run Chemical Co., Ltd

Contact:+86-0791-88521351

Address:XingHuo industrial zone in YongXiu county
U-Chemo Holding Co.,Limited

website:http://www.u-chemo.com

Contact:+86-21-61558312

Address:Dong Fang Road,
Shaanxi HuaTai Bio-fine chemical company Ltd

Contact:86-029-87862197

Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
SHENYANG COMEBOARD TECHNOLOGY CO., LTD

Contact:+86-24-25724626

Address:Room2210,Tianbao International Building,No.8-1 Weigong South Street,Tiexi District,Shenyang,China

Relevant to this article

The Walling, El-Taliawi, and Zhao "Carnonyl Effect" in Radical Brominations Is an Example of HBr Reversal. It Is Not Relevant to ? and ? Radical Chemistry.

Doi:10.1021/ja00318a050
(1984)
The hydrolysis of C₁₂ primary alkyl sulfates in concentrated aqueous solutions. Part 2. Influence of alkyl structure on hydrolytic reactivity in concentrated aqueous mixtures of sodium primary alkyl sulfates: 1-benzoyl-3-phenyl-1,2,4-triazole as a probe of water activity

Doi:10.1039/b102958b
(2001)
Catalytic dehydration of carbohydrates on in situ exfoliatable layered niobic acid in an aqueous system under microwave irradiation

Doi:10.1002/cssc.201300004
(2013)
Absolute rate constants and Arrhenius parameters for the addition of the methyl radical to unsaturated compounds: The methyl affinities revisited

Doi:10.1021/ja973128y
(1997)
Synthesis of REF₃ (RE = Nd, Tb) nanoparticles via a solvent extraction route

Doi:10.1016/j.materresbull.2009.02.001
(2009)
Infrared spectra of the very weak H2--HF and O2--HF complexes in solid neon

Doi:10.1063/1.451934
(1987)

Article Doi