Secondary isotope effects in dioxirane epoxidations. Concerted or step-wise mechanism?

DOI: 10.1016/0040-4039(96)01256-7

Source and publish data:

Tetrahedron Letters p. 5991 - 5994 (1996)

Update date:2022-08-17

Topics:

Authors:

Angelis, Yiannis

Zhang, Xiaojun

Orfanopoulos, Michael

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Article abstract of DOI:10.1016/0040-4039(96)01256-7

The inverse α- and β-secondary isotope effects found for the epoxidation reaction of dimethyl dioxirane (DMD) with alkenes support a non polar concerted mechanism.

Full text of DOI:10.1016/0040-4039(96)01256-7

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