Detection of Chlorophosphaethyne, , by Photoelectron Spectroscopy

DOI: 10.1039/ft9918700917

Source and publish data:

Journal of the Chemical Society - Faraday Transactions p. 917 - 920 (1991)

Update date:2022-08-16

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Authors:

Dennis, T. John

Firth, Steven

Kroto, Harold, W.

Matti, George, Y.

Mok, Chup-Yew

et al. et al.

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Article abstract of DOI:10.1039/ft9918700917

The new molecule chlorophosphaethyne, , has been produced by flow thermolysis of trichloromethylphosphonous dichloride, Cl3CPCl2, over granulated zinc at 530 deg C and its photoelectron spectrum has been recorded.All four bands expected below 21 eV have been detected and the first vertical ionization energy at 10.10 eV is assigned to the degenerate 4? orbital.The assignments are supported by ab initio SCF calculations.

Full text of DOI:10.1039/ft9918700917

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