Regioselective Schiff's base mediated deglycosidation of digitalis glycosides. New efficient synthesis of digoxigenin bis-digitoxoside and digoxigenin mono-digitoxoside

DOI: 10.1016/0040-4039(94)02212-T

Source and publish data:

Tetrahedron Letters p. 63 - 66 (1995)

Update date:2022-08-16

Topics:

Authors:

Adamczyk, Maciej

Grote, Jonathan

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Article abstract of DOI:10.1016/0040-4039(94)02212-T

Dialdehydes derived from digoxin glycosides via sodium periodate oxidation were regioselectively deglycosylated by various amino acids in anhydrous methanolic solution to afford excellent yields of digoxigenin bis-digitoxoside and digoxigenin mono-digitoxoside in a single step.

Full text of DOI:10.1016/0040-4039(94)02212-T

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