Tetrahedron Letters p. 5351 - 5354 (1982)
Update date:2022-08-17
Topics:
Minsky, Abraham
Meyer, Amatzya Y.
Rabinovitz, Mordecai
(1)H NMR chemical shifts of antiaromatic species reveal an enhanced paratropic displacement.The high-field shifts exhibited by doubly charged benzenoid polycycles were shown to be strongly related to the LUMO-HOMO energy gap in these antiaromatic systems.As the gap decreases, a larger paratropic shift was observed.
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