Journal of the Chemical Society. Chemical communications p. 182 - 183 (1990)
Update date:2022-08-17
Topics:
Takahashi, Tamotsu
Fujimori, Takayasu
Seki, Takashi
Saburi, Masahiko
Uchida, Yasuzo
et al.
Skeletal rearrangement of α-substituted organometallic compounds to give β-substituted compounds by carbon-carbon bond activation was performed with bis(η5-cyclopentadienyl)-2,5-dimethyl-zircona- or -hafna-cyclopentane, which were regio- and stereo-selectively converted into the corresponding 3,4-dimethylmetallacyclopentanes in high yields.
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