Activation and Orientation by Receptor-Substrate Binding. The Case of Acyl Transfer from O-Acetylhydroxylamine

DOI: 10.1246/cl.1987.215

Source and publish data:

Chemistry Letters p. 215 - 218 (1987)

Update date:2022-08-28

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Authors:

Lehn, Jean-Marie

Nishiya, Takako

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Article abstract of DOI:10.1246/cl.1987.215

The strong binding ability of the receptor molecule 1 induces complexation of O-acetylhydroxylamine and of hydroxylamine in their protonated forms; as a result, subsequent reaction of bound CH3COONH3⁺ becomes fast and selective, giving only acetic acid with a rate enhancement by a factor of about 30.

Full text of DOI:10.1246/cl.1987.215

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