Activation and Orientation by Receptor-Substrate Binding. The Case of Acyl Transfer from O-Acetylhydroxylamine

DOI: 10.1246/cl.1987.215

Source and publish data:

Chemistry Letters p. 215 - 218 (1987)

Update date:2022-08-28

Topics:

Authors:

Lehn, Jean-Marie

Nishiya, Takako

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1987.215

The strong binding ability of the receptor molecule 1 induces complexation of O-acetylhydroxylamine and of hydroxylamine in their protonated forms; as a result, subsequent reaction of bound CH3COONH3⁺ becomes fast and selective, giving only acetic acid with a rate enhancement by a factor of about 30.

Full text of DOI:10.1246/cl.1987.215

Products guided by the article

Product name:Acetohydroxamic acid

Cas No:546-88-3

R&D Labs maybe for 546-88-3

Anqing World Chemical Co., Ltd.

Contact:+86-556-5800026

Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Taizhou Chemedir Biopharm-tech Co., Ltd

Contact:+86 523 86200218

Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Tianjin Emulsion Science&Technology Development Co.,Ltd

Contact:13901380442

Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China

Relevant to this article

Synthesis of enantiomerically pure forms of trans-3-phenylglycidic acid.

Doi:10.1016/S0040-4039(96)02426-4
(1997)
Doi:10.1021/jo01256a096
(1969)
Doi:10.1007/BF00962024
()
Synthesis of 1,2-naphthalenediol derivatives by Rh-catalyzed intermolecular O[sbnd]H insertion reaction of 1,2-diazonaphthoquinones with water and alcohols

Doi:10.1016/j.tetlet.2017.07.084
(2017)
Tetranuclear complexes composed of dinickel(II) macrocyclic fragments bridged by 5,5′-(1,3-phenylene)bis-1H-tetrazolato and N,N-bis(tetrazol-5- ato)amine coligands: Synthesis, structures and magnetic properties

Doi:10.1016/j.poly.2012.09.027
(2013)
Palladium-Catalyzed Regioselective Hydroarylation of Ynamides with Aryl Iodides: Easy Synthesis of Various Substituted Enamides Containing Stilbene Derivatives

Doi:10.1055/s-0036-1588874
(2017)

Article Doi