Enantioselective Synthesis of erythro-β-Hydroxy-L-histidine, the Pivotal Amino Acid of Bleomycin-Fe(II)-O2 Complex

DOI: 10.1246/cl.1988.83

Source and publish data:

Chemistry Letters p. 83 - 86 (1988)

Update date:2022-08-11

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Authors:

Owa, Takashi

Otsuka, Masami

Ohno, Masaji

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Article abstract of DOI:10.1246/cl.1988.83

erythro-β-Hydroxy-L-histidine, a novel amino acid constituent of bleomycin, has been synthesized enantioselectively via the reaction of (N-pyruvylideneglycyl-D-phenylalaninato)copper(II) with imidazole-4-carbaldehyde.

Full text of DOI:10.1246/cl.1988.83

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