
Bioscience, Biotechnology and Biochemistry p. 453 - 458 (1998)
Update date:2022-08-17
Topics:
Nakajima, Noriyuki
Ubukata, Makoto
A facile synthetic route is described to cyanogenic glycosides (R)-prunasin, linamarin and (S)-heterodendrin from O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)trichloroacetimidate and the corresponding α-hydroxyamides by a 3-step reaction of glycosylation, cyanohydrin formation by dehydration of carboxamides, and deprotection.
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