Hydroformylation of 1,6-Dienes with Carbonylhydridotris(triphenylphosphine)rhodium

DOI: 10.1039/P19830001929

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1929 - 1935 (1983)

Update date:2022-08-30

Topics:

Authors:

Grigg, Ronald

Reimer, Gerald J.

Wade, Alan R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19830001929

Hydroformylation of a number of 1,6-dienes has been achieved at room temperature and atmospheric pressure using as catalyst.Octa-1,6-dienes are hydroformylated specifically at the terminal double bond and good selectivity for the n-aldehyde is observed when a 2:1 mixture of hydrogen and carbon monoxide are used.Both mono- and di-formyl derivatives are formed from 4,4-diacetylhepta-1,6-diene, with a strong preference for n-aldehydes.The effect of catalyst concentration on product distribution is reported.Octa-1,3,7-triene can be selectively hydroformylated by protecting the diene moiety as its cycloadduct with sulphur monoxide or dioxide, and whilst methylenecyclopentane undergoes regiospecific hydroformylation, methylenecyclobutane is isomerised to methylcyclobutene.

Full text of DOI:10.1039/P19830001929

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Cyclopentyl Acetaldehyde

Cas No:5623-81-4

R&D Labs maybe for 5623-81-4

JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD

website:http://www.xypharm.com/

Contact:+86-515-84383317

Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
Zhejiang Hoshine Silicon Industry Co., Ltd.

Contact:86-573-89179966

Address:Zhapu Town, Pinghu City, Zhejiang, China
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China
Tengzhou Runlong Fragrance Co., Ltd.

website:http://www.tzrunlong.com/

Contact:0086-15665710862

Address:No. 78, Fushan Road, Biomedical Industrial Park, Dawu Town, Tengzhou, Shandong, 277514 China
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.

Relevant to this article

N-Alkenyl nitrone dipolar cycloaddition routes to piperidines and indolizidines. Part 8. The scope of tandem reactions involving hydroxylamine-alkyne cyclisations

Doi:10.1016/0040-4020(96)00643-6
(1996)
Highly efficient energy transfer in the light harvesting system composed of three kinds of boron-dipyrromethene derivatives

Doi:10.1021/ol702381j
(2008)
Novel gemini micelles from dimeric surfactants with oxyethylene spacer chain. Small angle neutron scattering and fluorescence studies

Doi:10.1021/jp980836c
(1998)
Doi:10.1021/jo01099a603
(1958)
METHANDROSTENOLONE. MECHANISM OF HYDROCHLORIC ACID INDUCED FLUORESCENCE.

Doi:10.1002/jps.2600530211
(1964)
Doi:10.1080/01431160118022
()

Article Doi