Pulse Radiolysis and E.S.R. Evidence for the Formation of an Alkene Radical Cation in Aqueous Solution

DOI: 10.1039/c39870000208

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 208 - 210 (1987)

Update date:2022-08-28

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Authors:

Asmus, Klaus-Dieter

Williams, Peter S.

Gilbert, Bruce C.

Winter, Jeremy N.

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Article abstract of DOI:10.1039/c39870000208

Direct pulse radiolysis evidence, complemented by e.s.r. experiments, establishes that the radical cation Me2C⁼-C^.Me2 (λ_max ca. 290 nm) is formed by acid-catalysed elimination of OH^- from .CMe2CMe2OH; the radica

Full text of DOI:10.1039/c39870000208

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