Inorganic Chemistry p. 259 - 262 (1980)
Update date:2022-08-16
Topics:
Kikkawa, Shinichi
Kanamaru, Fumikazu
Koizumi, Mitsue
An organic derivative of the layer compound FeOCl was obtained by the reaction of an intercalated compound FeOCl-(4-NH2py)1/4 and ethylene glycol C2H4(OH)2 at 110°C for 6 days. The reaction product was a brown crystal of flake shape. Its basal spacing was 14.5 A? when the product was still in ethylene glycol, but it shrank to 10.98 A? by washing with acetone. The chemical composition of the final product was FeO(O2C2H4)1/2. Mo?ssbauer isomer shift and quadrupole splitting were respectively 0.38 mm/s and 0.59 mm/s at room temperature. Thermal analysis and the infrared spectrum suggested a substitution of ethylene glycolate anions O2C2H42- for chloride ions in the FeOCl layer. A possible layer structure derived from FeOCl is proposed.
Contact:+86-21-54391580
Address:Room 502,No.65,Lane 2388 Hongxin Road,Shanghai,China
Shanghai Goyic Pharmaceutical&Chemical Co,. Ltd
Contact:+86-021-60275964
Address:No. 528 ruiqing road
FUJIAN SHANSHUI CHEMICAL CORP.LTD.
Contact:+86-151-59920036
Address:Jinqiao Gareden, jo@fj-xinyi.com
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)
Contact:+86-571-56880228
Address:15F Guodu development Building, NO.182 Zhaohui Road
Shanghai Micro-mega Industry Co., Ltd.
Contact:0086-21-34628682;57153848
Address:Rm413,No.413,West Meilong Road, Minhang District,Shanghai P R China
Doi:10.3987/com-99-8566
(1999)Doi:10.1016/j.tca.2014.10.015
(2014)Doi:10.1016/j.physb.2004.12.063
(2005)Doi:10.1021/jo01081a603
(1960)Doi:10.1021/ol051675f
(2005)Doi:10.1007/s11172-013-0194-y
(2013)
