Helvetica Chimica Acta p. 1253 - 1261 (1983)
Update date:2022-08-30
Topics:
Keller-Schierlein, Walter
Wuthier, Damian
Drautz, Hannelore
From the cultures of Streptomyces fimbriatus, strain Tue 2335, the title compound 1 was isolated by solvent extraction, chromatography, and distillation.Its constitution was determined by spectroscopic investigations of 1 and some of its derivatives, and the chirality by transformation to (R)-1,3-isopropylidenedioxydecane (12); a reference sample of the latter was prepared from (R)-methyl 3-hydroxydecanoate (10).In the equilibrium mixture the keto form 1 predominates the two hemiacetals 2a and 2b.Compound 1 is inactive against bacteria, yeasts and fungi.
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