A linear free energy correlation between solvent parameter ET(30) and stereoselectivity in the condensation of phenylmagnesium bromide with (±)-3-phenylbutanone.

DOI: 10.1016/S0040-4039(00)92776-X

Source and publish data:

Tetrahedron Letters p. 1565 - 1566 (1980)

Update date:2022-08-25

Topics:

Authors:

Perez-Ossorio

Perez-Rubalcaba

Quiroga Quiroga

Lasperas

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A direct influence of the solvent on the RS,SR/RR,SS ratio in nucleophilic additions of phenylmagnesium bromide to (±)-3-phenylbutanone is reported.

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