
Tetrahedron Letters p. 3897 - 3898 (1980)
Update date:2022-08-22
Topics:
Saimoto, Hiroyuki
Hiyama, Tamejiro
Nozaki, Hitosi
Sulphuric acid catalyzed ring closure of propargyl alcohol dianion adduct of 2-cyclododecenone gives bicyclo[10.3.0]pentadec-1(12),2-dien-13-one. 1,6-Conjugate addition of methyl group followed by ring-expansion and aromatization affords the title compounds.
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Doi:10.1021/jo01310a058
(1980)Doi:10.1080/00222890209601955
(1949)Doi:10.1016/S0223-5234(99)00221-4
(1999)Doi:10.1021/ja01655a004
(1923)Doi:10.1002/anie.201410207
(2015)Doi:10.1016/0009-2614(90)85029-C
(1990)