Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1497 - 1502 (1981)
Update date:2022-08-29
Topics:
Fox, Malcolm F.
Smith, Clifford B.
Hayon, Elie
The far-ultraviolet solution of very dilute thiocyanate ion in a range of solvents shows that there are at least three absorption bands labelled A, D and E.All three bands are shown to have charge-transfer-to-solvent charasteristics, in contrast to some previous reports.The conflicting previous reports of the spectroscoy and photochemistry of thiocyanate ions, together with the current work, are resolved in terms of a spectroscopic transition scheme involving a forbidden at ca. 36 000 cm-1, which is normally extremely weak or not detectable.The transition is only detected at high contrentrations of salt.The first allowed transition is expected to occur at ca. 62 000 cm-1.Within this scheme the c.t.t.s. bands occur (in aqueous solution) at 46 000 and 53 500 cm-1.A further band is observed in red-shifting solvents at ca. 57 000 cm -1.The temperature sensitivities of the three c.t.t.s. bands, relative to the solvated electron, are 0.58, 0.47 and 0.30.
Guangzhou Reachin Chemical Co., Ltd
Contact:+86-20-37087379 ext.604
Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
QINGDAO NEW FLOURISH INTERNATIOANAL TRADE CO., LTD.
Contact:+86 532 80861829
Address:No. 1, Yinchuan East Road, 266061, Qingdao, China
LinHai Cina Chemical Co., LTD.
Contact:0576-85580989
Address:Pharma-chem zone,Duqiao,Linhai,Zhejiang,China
ShenZhen InnoSyn Biotech Co.,Ltd
website:http://www.innosyns.com
Contact:+86-755-28351685
Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District
SICHUAN TONGSHENG AMINOACID CO.LTD
website:http://www.aminoacid.cc
Contact:86-838-2274206/2850606
Address:Room 1-11-1,No.19 of North TianShan Road,Deyang,Sichuan China
Doi:10.1039/C6CC08905D
(2017)Doi:10.1016/S0022-328X(00)88681-7
(1972)Doi:10.1016/j.cclet.2015.07.005
(2015)Doi:10.1007/BF00628476
(1960)Doi:10.1007/s11243-019-00366-8
(2020)Doi:10.1016/0040-4020(76)80037-3
(1976)
