INVESTIGATIONS OF CHROMIUM(III), MAGANESE(III), TIN(II) AND LEAD(II) DITHIOCARBAMATE COMPLEXES

Article abstract of DOI:10.1016/0022-2860(80)85202-1

Piperidine-, morpholine-4-, N-methylpiperazine-4- and thiomorpholine-4-carbodithioate complexes of chromium(III), manganese(III), tin(II) and lead(II) are prepared and characterized by chemical analyses, spectroscopic methods (I.R. and electronic spectra), magnetic susceptibilities, conductivity measurements and mass spectra.The complexes are of the type M(R2dtc)_n, where n is the oxidation number of the metal ion.Where possible a tentative stereochemistry of the complexes is discussed on the basis of the results obtained.In all the complexes the dithiocarbamate ligands show bidentate behaviour.