Chemistry Letters p. 2005 - 2008 (1988)
Update date:2022-08-16
Topics:
Okamoto, Yasuaki
Kane, Hiroshige
Imanaka, Toshinobu
Molybdenum carbonyls encaged in a NaY zeolite were found to form stable butadiene complexes; Mo(CO)4(C4H6) and Mo(CO)2(C4H6)n (n = 1 or 2).These complexes are implied to deactivate the hydrogenation of C4H6 over molybdenum carbonyls/zeolite catalysts.The active species is proposed to be Mo(CO)3 ads.
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