Tetrahedron Letters p. 5803 - 5806 (1985)
Update date:2022-08-17
Topics:
Asami, Masatoshi
cis-4-t-Butyldimethylsiloxy-2-cyclopenten-1-ol and cis-4-tetrahydropyranyloxy-2-cyclopenten-1-ol were obtained with high enantiomeric excesses (ee) by the reaction of cis-3,4-epoxycyclopentan-1-ol derivatives with chiral lithium amide.An application to the syntheses of both (S)- and (R)-4-hydroxy-2-cyclopentenone was demonstrated.
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