Monomolecular Heterocyclic Rearrangements. Part 7. Evidence for General Base Catalysis in the Rearrangement of the Z-Phenylhydrazone of 3-Benzoyl-5-phenyl-1,2,4-oxadiazole into 2,5-Diphenyl-4-benzoylamino-1,2,3-triazole in Dioxan-Water

DOI: 10.1039/P29810001325

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1325 - 1328 (1981)

Update date:2022-08-11

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Authors:

Frenna, Vincenzo

Vivona, Nicolo

Consiglio, Giovanni

Corrao, Antonino

Spinelli, Domenico

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Article abstract of DOI:10.1039/P29810001325

The title reaction has been studied at various pS⁺ and buffer concentrations.Kinetic constants for uncatalysed and catalysed pathways have been calculated.A mechanism for the rearrangement is offered.

Full text of DOI:10.1039/P29810001325

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