Unusual course of “enolate-imine” condensation in approach to β-lactams

DOI: 10.1134/S1070428017050220

Source and publish data:

Russian Journal of Organic Chemistry p. 787 - 789 (2017)

Update date:2022-08-16

Topics:

Authors:

Valiullina

Gimalova

Spirikhin

Miftakhov

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1134/S1070428017050220

In reaction of methyl (Е)-3-(methoxycarbonyl)methylimino-2,2-dimethylpropanoate with enolate of ethyl 3-hydroxybutanoate an abnormal reaction product was isolated, 2-methyl 4-ethyl-(2S*,3S*,4S*,5S*)-3-methyl-5-(2-methyl-1-methoxy-1-oxopropan-2-yl)pyrrolidine-2,4-dicarboxylate.

Full text of DOI:10.1134/S1070428017050220

Products guided by the article

Product name:methyl glycinate

Cas No:616-34-2

R&D Labs maybe for 616-34-2

Basilea Pharmaceutica China Ltd.

Contact:+86-513-82198075

Address:No.638 Xiushan Road(East),Haimen, Jiangsu 226100, P.R.China
Eastar Chemical Corporation

website:http://www.eastarchem.com/

Contact:1-800-898-2436

Address:1215 K Street, STE 1700
Jiangsu Taihu New Materials Holding Co., Ltd

Contact:+86-519-86160108

Address:Xueyan Town, Changzhou City, Jiangsu Province, 213169, China
Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai

Relevant to this article

Some thiocarbamoyl based novel anticathepsin agents

Doi:10.1016/j.bioorg.2020.104174
(2020)
Discovery and development of novel pyrimidine and pyrazolo/thieno-fused pyrimidine derivatives as potent and orally active inducible nitric oxide synthase dimerization inhibitor with efficacy for arthritis

Doi:10.1016/j.ejmech.2021.113174
(2021)
Amine-catalyzed direct aldol reactions of hydroxy- and dihydroxyacetone: Biomimetic synthesis of carbohydrates

Doi:10.1021/jo500860g
(2014)
Acetylacetonate bis(thiosemicarbazone) complexes of copper and nickel: Towards new copper radiopharmaceuticals

Doi:10.1039/b406429a
(2004)
Short and efficient syntheses of protoberberine alkaloids using palladium-catalyzed enolate arylation

Doi:10.1002/anie.201409164
(2014)
Straightforward chemo- and stereoselective fluorocyclopropanation of allylic alcohols: Exploiting the electrophilic nature of the not so elusive fluoroiodomethyllithium

Doi:10.1039/c9cc03394g
(2019)

Article Doi