Chemistry Letters p. 447 - 448 (1995)
Update date:2022-08-11
Topics:
Moon, Sang-Chul
Hieida, Takeshi
Yamashita, Hiromi
Anpo, Masakazu
The photocatalyzed isomerization of cis-2-butene has been investigated on active ZrO2 catalysts which exhibited a typical photoluminescence associated with low coordinated surface sites.A geometrical isomerization reaction occurred predominantly and with high efficiency under UV-irradiation of the ZrO2 catalyst in the presence of cis-2-butene.A good parallel between the photoluminescence intensity and the rate of photocatalytic activity clearly indicated that the low coordinated surface sites play a significant role in the photocatalytic isomerization of cis-2-butene on the active ZrO2 catalysts.
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