Journal of Organic Chemistry p. 5627 - 5631 (1985)
Update date:2022-08-30
Topics:
Nair, Vasu
Offerman, Rick J.
Purine and pyrimidine bases react with epoxy carbonyl compounds in aqueous solution to yield ring-extended adducts.These products include etheno-modified bases as well as adducts in which the modification involves the formation of an additional six-membered ring.The latter examples are among the first known cases of this type of modification of pyrimidine bases.Plausible mechanisms for the formation of these adducts are discussed.
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