Journal of Organometallic Chemistry p. 1 - 10 (1994)
Update date:2022-08-23
Topics:
Laduranty, Joelle
Miginiac, Leone
Allylic Grignard reagents easily react through addition and elimination, with the two methylthio groups of 2,5-bis(methylthio)-1,3,4-thiadiazole, and with the one methylthio group of 5-methylthio-1,3,4-thiadiazol-2(3H)-thione, to lead to symmetrical or unsymmetrical disubstituted derivatives of 1,3,4-thiadiazole.Key words: Magnesium; Thiadiazole; Addition-elimination reaction
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