Journal of Organic Chemistry p. 260 - 265 (1981)
Update date:2022-08-22
Topics:
Villarreal, Jose A.
Grubbs, Edward J.
Thermal decompositions of N-benzhydryl-α,α-diphenylnitrone (1) and the para-tetradeuterated analogue 1-d4 in several solvents are reported.Mass spectral analyses of recovered nitrones and/or O-benzhydryl ethers were performed.These data are combined with previously reported spectroscopic rate constants for the decomposition of 1 to evaluate the true carbon-nitrogen homolysis rate constant and the relative rate constants for (a) geminate radical recombination at the iminoxy nitrogen, (b) irreversible recombination at oxygen, and (c) diffusion of the solvent-caged radicals.
View More
website:http://pharmchemlabs.lookchem.com/
Contact:+86-576-88283887
Address:Yantou Chemical Industry Zone,Jiaojiang
Contact:86-25-84683399
Address:605, Phoenix Herui Plaza, No.389, South Taiping Road, Nanjing, China 210002
website:http://www.dulynet.com/
Contact:025-84699383 -8003
Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Nantong Auxin Electronic Technology Co., LTD
Contact:86-513-88760026
Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
GUANGZHOU MEDCAN PHARMATECH LTD
website:http://www.gzmedcan.com
Contact:+86-20-82519649
Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China
Doi:10.1016/j.apcata.2015.06.024
(2015)Doi:10.1021/jo01089a022
(1959)Doi:10.3390/molecules15053276
(2010)Doi:10.1016/j.catcom.2013.11.003
(2014)Doi:10.1039/jr9630002351
(1963)Doi:10.1016/0022-1139(94)03084-D
(1995)
