Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1677 - 1682 (1989)
Update date:2022-08-12
Topics:
Volod'kin, A. A.
Zaitsev, A. S.
Rubailo, V. L.
Belyakov, V. A.
Zaikov, G. E.
A mechanism is proposed for the reaction of 2,6-di-tert-butylphenol with methyl acrylate in the presence of potassium 2,6-di-tert-butylphenoxide and KOH and, based on a computer calculation of the kinetic scheme, the constants have been found for the elementary stages of the reaction, sufficient to interpret the experimental data.The alkylation of 2,6-di-tert-butylphenol by methyl acrylate takes place by an inhibited catalytic chain mechanism involving the participation of ion pairs in the reaction.
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