Syntheses of Strychnos- and Aspidospermatan-Type Alkaloids. 6. Total Syntheses of (+/-)-Echitamidine, (+/-)-Alstogustine, (+/-)-19-epi-Alstogustine, and (+/-)-Akuammicine

DOI: 10.1021/jo00104a042

Source and publish data:

Journal of Organic Chemistry p. 7803 - 7806 (1994)

Update date:2022-08-18

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Authors:

Kuehne, Martin E.

Xu, Feng

Brook, Christopher S.

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Article abstract of DOI:10.1021/jo00104a042

19-Oxodihydroakuammicine was obtained in a three-pot sequence, in 25percent overall yield based on a new condensation-sigmatropic rearrangement sequence.Reductions and quaternization reactions furnished the title compounds.

Full text of DOI:10.1021/jo00104a042

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