Journal of the Chemical Society. Chemical communications p. 988 - 989 (1990)
Update date:2022-08-29
Topics:
Ito, Takashi
Koga, Miho
Kurishima, Susumu
Natori, Makoto
Sekizuka, Norihiro
Yoshioka, Ken-ichiro
The system consisting of (η5-C5H5)2MoH2 and protonic acids such as RCO2H, HCl, and p-MeC6H4SO3H reduced aldehydes and ketones under mild conditions chemoselectively; an extremely high diastereoselectivity was achieved by using the reaction intermediate (η5-C5H5)2Mo(H)OSO2C6H4Me-p in the reduction of 4-t-butylcyclohexanone.
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