Journal of the Chemical Society. Chemical communications p. 494 - 495 (1987)
Update date:2022-08-29
Topics:
Foyentin, Muriel
Folcher, Gerard
Ephritikhine, Michel
Treatment of cp3U(THF) (1) (cp = η-C5H5, THF = tetrahydrofuran) with diphenylacetylene affords the alkyne complex cp3U(Ph-C<*>C-Ph); (1) reacts with RLi (R = Me, Bun) to give the alkyl compounds cp3URLi (3); hydrogenolysis of (3) in the presence of a terminal alkene R'(-H) leads to the formation of cp3UR'Li.
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