A new approach to (+)-brefeldin A via a nickel-catalyzed coupling reaction of cyclopentenyl acetate and lithium 2-furylborate

DOI: 10.1016/0040-4039(96)01291-9

Source and publish data:

Tetrahedron Letters p. 6125 - 6128 (1996)

Update date:2022-08-11

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Authors:

Kobayashi, Yuichi

Watatani, Kengo

Kikori, Yuusuke

Mizojiri, Ryo

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Article abstract of DOI:10.1016/0040-4039(96)01291-9

Coupling reaction of 2 with 2-furylborate 14 in the presence of the nickel catalyst afforded 1,4-isomer 5 regio- and stereoselectively and the product 5 was applied to the synthesis of Bartlett's brefeldin intermediate 11.

Full text of DOI:10.1016/0040-4039(96)01291-9

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