Tetrahedron Letters p. 1103 - 1104 (1982)
Update date:2022-08-10
Topics:
L'abbe, Gerrit
Deketele, Martine
Dekerk, Jean-Paul
The reaction of 4-carbethoxy-5-chloro-1,2,3-thiadiazole (1) with sodium azide results in the formation of ethyl α-thiatriazolyldiazoacetate (3) instead of the corresponding azide (2).Two plausible mechanisms for this new rearrangement are formulated.
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