Anomaluos Effects during Aromatic Nucleophilic Photosubstitutions of 2- and 4-Fluoroanisoles in Solvent Mixtures of Water and tert-Butyl Alcohol

DOI: 10.1021/jo00219a052

Source and publish data:

Journal of Organic Chemistry p. 3655 - 3657 (1985)

Update date:2022-08-16

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Authors:

Liu, Jerry H.

Weiss, Richard G.

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Article abstract of DOI:10.1021/jo00219a052

The rate constant ratio for removal of fluorine by either cyano or hydroxy during aromatic nucleophilic photosubstitutions on 2- or 4-fluoroanisole displays a remarkable dependence upon the composition of the water/tert-butyl alcohol solvent and the distance between the methoxy group and the site of substitution in the solutes.

Full text of DOI:10.1021/jo00219a052

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