
Tetrahedron Letters p. 5277 - 5280 (1990)
Update date:2022-08-28
Topics:
Mitchell, Reginald H.
Zhou, Pengzu
The macrocyclic "benzyne" 3 was trapped with furan and several annelated furans.The adducts were deoxygenated by Fe2(CO)9 in a fast route to yield several new annelated dihydropyrenes.Molecular mechanics calculations indicate that the strain energy of 3 is similar to benzyne.
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