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Effects of Oxygen on Cyclic Voltammetry of Olefins. A Diagnostic Tool for Elucidating the Reactivity of Olefin Radical Cations with Molecular Oxygen

DOI: 10.1246/cl.1986.1727

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Chemistry Letters p. 1727 - 1730 (1986)

Update date:2022-08-18

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Authors:

Tsuchiya, MasahiroTsuchiya, Masahiro

Akaba, RyoichiAkaba, Ryoichi

Aihara, ShinAihara, Shin

Sakuragi, HirochikaSakuragi, Hirochika

Tokumaru, KatsumiTokumaru, Katsumi

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Article abstract of DOI:10.1246/cl.1986.1727

The oxidation currents of olefins were measured under cyclic voltammetry conditions in the absence and presence of oxygen.Under oxygen the currents decreased to different extents depending on the structure of olefins.The mechanism of the oxygen effect are discussed in connection with elucidation of the reactivity of olefin radical cations with molecular oxygen.

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Full text of DOI:10.1246/cl.1986.1727

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