Tetrahedron Letters p. 2867 - 2870 (1988)
Update date:2022-07-30
Topics:
Roberts, David A.
Organomagnesium chemistry plays a crusial role in the stereoselective construction of the two tri-substituted alkenes in the diol (3)-a key intermediate in a synthesis of the spasmogenic diterpenoid zoapatanol (1).A Ni(0)-catalysed coupling of MeMgBr with a dihydrofuran gives the C(6)-C(7) alkene; carbomagnesiation or hydromagnesiation of acetylene intermediates gives the C(2)-C(3) alkene.
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