An efficient synthesis of enantiopure 1-alkoxy-1,2-propadienes from propargyl bromide

DOI: 10.1055/s-1994-25577

Source and publish data:

Synthesis p. 795 - 799 (1994)

Update date:2022-08-23

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Authors:

Rochet Rochet

Vatele Vatele

Gore Gore

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Article abstract of DOI:10.1055/s-1994-25577

A number of enantiopure functionalized alcohols have been O-allenylated by reaction of their corresponding sodium alcoholates with propargyl bromide followed by t-BuOK catalyzed isomerization of the resulting propargyl ethers, in good overall yields.

Full text of DOI:10.1055/s-1994-25577

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